Uranium diboride

Uranium boride
Uranium boride
Identifiers
CAS Number
  • 12007-36-2 checkY
3D model (JSmol)
  • Interactive image
ChemSpider
  • 74717
ECHA InfoCard 100.031.358 Edit this at Wikidata
EC Number
  • 234-508-0
PubChem CID
  • 82795
CompTox Dashboard (EPA)
  • DTXSID901045484 Edit this at Wikidata
InChI
  • InChI=1S/2B.U
    Key: QPXOIGGWJBMJIH-UHFFFAOYSA-N
  • B#[U]#B
Properties
Chemical formula
UB2
Molar mass 259.651 g/mol
Density 12.7 g/cm3
Melting point 2,430 °C (4,410 °F; 2,700 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)
Infobox references
Chemical compound

Uranium boride (UB2), a compound of uranium and boron, is a very stable glassy boride material that is insoluble in water.

It is being explored as an ingredient in high entropy alloys, and as a method of immobilizing uranium-based radioactive waste, and rendering it safe for long-term storage. It has some applications in endocurietherapy, a method of radiation therapy wherein radioactive microspheres are implanted directly into the treatment site and allowed to remain for an extended period of time, may also use this class of material as it would not be attacked while in situ.

It is being considered as a nuclear fuel material as it has a high density and thermal conductivity[1]

References

  1. ^ Watkins, Jennifer K.; Wagner, Adrian R.; Gonzales, Adrian; Jaques, Brian J.; Sooby, Elizabeth S. (2022). "Challenges and opportunities to alloyed and composite fuel architectures to mitigate high uranium density fuel oxidation: Uranium diboride and uranium carbide". Journal of Nuclear Materials. 560: 153502. Bibcode:2022JNuM..56053502W. doi:10.1016/j.jnucmat.2021.153502. OSTI 1862689. S2CID 245646534.
  • US patent 5342283, Roger R. Good, "Endocurietherapy", issued 1994-08-30 
  • Franzen, Harald (6 April 2001). "Cheap, Safe Storage for Radioactive Materials". Scientific American. Retrieved 21 November 2011.
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U(II)
U(III)
  • UF3
  • UCl3
  • UBr3
  • UI3
  • UP
  • U(OH)3
  • UH3
  • UN
Organouranium(III) compounds
  • U(C5H5)3
  • U(IV)
    • U(BH4)4
    • UC
    • UCl4
    • UF4
    • UBr4
    • UI4
    • UO2
    • UH4
    • USi2
    • US2
    • USe2
    • UTe2
    • U(SO4)2
    Organouranium(IV) compounds
  • U(C8H8)2
  • U(C5H5)4
  • U(C5H5)3Cl
  • U(IV,V)
    • U2N3
    U(IV,VI)
    • U3O8
    U(V)
    • UCl5
    • UF5
    • UBr5
    • UI5
    • U2O5
    U(VI)
    • (NH4)2U2O7
    • Na2U2O7
    • UCl6
    • UF6
    • U(PO4)2
    • UO3
    • UO4
    • UO2(CH3COO)2
    • UO2(CHO2)2
    • UO2CO3
    • UO2CO3·2(NH4)2CO3
    • UO2Cl2
    • UO2F2
    • UO2(NO3)2
    • UO2(OH)2
    • (UO2)2(OH)4
    • UO2(SO4)2
    • ZnUO2(CH3COO)4
    • UN2
    • H2UO4
    • Na4UO2(CO3)3
    U(XII)
    • UO6 (hypothetical)
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    Borides Bxy-
    BxHy He
    Li Be B C N O F Ne
    Na MgB2 AlB2
    AlB12
    SiBx P S Cl Ar
    K CaB4
    CaB6
    ScB12 TiB2 V CrB Mn FeB4
    FexBy
    CoxBy Ni3B
    Ni2B
    Cu Zn Ga Ge As Se Br Kr
    Rb SrB6 YBx ZrB2 NbB2 Mo Tc RuBx Rh Pd Ag Cd In Sn Sb Te I Xe
    Cs BaB6 * LuB4
    LuB6
    HfB2 TaBx WxBy ReB2 OsBx Ir Pt Au Hg Tl Pb Bi Po At Rn
    Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
     
    * LaB4
    LaB6
    CeB4
    CeB6
    PrB4
    PrB6
    NdB4
    NdB6
    Pm SmB4
    SmB6
    EuB6 GdB4
    GdB6
    TbB4
    TbB6
    DyB4
    DyB6
    HoB4
    HoB6
    ErB4
    ErB6
    TmB4
    TmB6
    YbB4
    YbB6
    ** Ac Th Pa UB2 Np PuBx Am Cm Bk Cf Es Fm Md No


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