Hans von Pechmann : Life, Works, Notes Wikipedia, the free encyclopedia

Hans von Pechmann

German chemist (1850–1902)

Hans von Pechmann

Born	1 April 1850 Nürnberg, Kingdom of Bavaria, German Empire
Died	19 April 1902(1902-04-19) (aged 52) Tübingen, Kingdom of Württemberg, German Empire
Nationality (legal)	German
Alma mater	University of Greifswald
Known for	Pechmann condensation Diazomethane
Scientific career
Fields	organic chemistry
Institutions	University of Munich University of Tübingen
Doctoral advisor	Heinrich Limpricht
Doctoral students	William Hobson Mills Julius B. Cohen

Hans Freiherr^[a] von Pechmann (1 April 1850 – 19 April 1902) was a German chemist, renowned for his discovery of diazomethane in 1894.^[1]^[2] Pechmann condensation^[3]^[4] and Pechmann pyrazole synthesis.^[5] He also first prepared 1,2-diketones (e.g., diacetyl), acetonedicarboxylic acid, methylglyoxal and diphenyltriketone; established the symmetrical structure of anthraquinone.

Von Pechmann also produced the first example of solid polyethylene serendipitously in 1898, via the decomposition of diazomethane.

Life

Von Pechmann was born in Nürnberg, the only son of a doctor, who was also named Hans. The von Pechmanns had distinguished themselves as soldiers; in 1702, von Pechmann's ancestor Martin Günther von Pechmann, a general of artillery in the Bavarian army, had been raised to the rank of a baron of the Holy Roman Empire by Leopold I.^[6] After studying with Heinrich Limpricht at the University of Greifswald he became professor at the University of Munich till 1895. He was professor at the University of Tübingen from 1895 until his death. He killed himself by taking cyanide, aged 52.^[6]

Works

Volhard's Anleitung zur Qualitativen chemischen Analyse . Chemisches Labolatorium des Staates, München 9th & 10th ed. 1901 Digital edition by the University and State Library Düsseldorf
Anleitung zur quantitativen Analyse nach Cl. Zimmermann : zum Gebrauche im chemischen Laboratorium des Staates zu München . Chemisches Laboratorium des Staates, München 10th ed. 1901 Digital edition by the University and State Library Düsseldorf

Notes

^ Regarding personal names: Freiherr is a former title (translated as Baron). In Germany since 1919, it forms part of family names. The feminine forms are Freifrau and Freiin.

References

^ H. von Pechmann (1894). "Ueber Diazomethan". Berichte der deutschen chemischen Gesellschaft. 27 (2): 1888–1891. doi:10.1002/cber.189402702141.
^ H. von Pechmann (1895). "Ueber Diazomethan". Berichte der deutschen chemischen Gesellschaft. 28 (1): 855–861. doi:10.1002/cber.189502801189.
^ H. von Pechmann, Carl Duisberg (1883). "Ueber die Verbindungen der Phenole mit Acetessigäther". Berichte der deutschen chemischen Gesellschaft. 16 (1): 2119–2128. doi:10.1002/cber.188301602117.
^ H. von Pechmann (1884). "Neue Bildungsweise der Cumarine. Synthese des Daphnetins". Berichte der deutschen chemischen Gesellschaft. 17 (1): 929–936. doi:10.1002/cber.188401701248.
^ H. von Pechmann (1898). "Pyrazol aus Acetylen und Diazomethan". Berichte der deutschen chemischen Gesellschaft. 31 (3): 2950–2951. doi:10.1002/cber.18980310363.
^ ^a ^b Koenigs, Wilhelm (1903). "Hans von Pechmann". Berichte der Deutschen Chemischen Gesellschaft. 36 (4): 4417–4511. doi:10.1002/cber.190303604134.